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Sustainable Polymers and Composite
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Sustainable Polymers and Composite
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Academic year 2022/2023
- Course ID
- CHI0161
- Teaching staff
- Prof. Maria Paola Luda (Lecturer)
Dott. Fabrizio Caldera (Lecturer)
Prof. Francesco Trotta (Lecturer)
Adrián Matencio Durán (Lecturer) - Degree course
- Materials Science
- Year
- 2nd year
- Teaching period
- First semester
- Type
- Characterizing
- Credits/Recognition
- 8
- Course disciplinary sector (SSD)
- CHIM/04 - industrial chemistry
- Delivery
- Class Lecture + Lab Practicals
- Language
- English
- Attendance
- Obligatory
- Type of examination
- Oral
- Prerequisites
- Priciples of Organic Chemistry, Basic of macromolecular chemistry, Chemical thermodynamics: classical and statistical.
- Propedeutic for
- self sustaing course. Master Degree thesis of macromolecular subject
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Sommario del corso
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Course objectives
According to the Master course objectives, in this course the sustainability of polymer materials is defined. Management of polymer systems in view of a circular economy is given.
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Results of learning outcomes
Understanding the structure and the properties of sustainable polymers
Knowing the principal characterization techniques of polymer materials.
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Course delivery
The course is delivered as:
face to face lectures: 48 h
and laboratory experiences: 32h
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Learning assessment methods
Exam is an oral interview during 30-45 min
The evaluation of the laboratory notebook will contribute to the definition of the final grade
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Program
Theoretical part (6 CFU)
- Definition of sustainable polymer, Main categories : natural polymers (proteins, polysaccharides, lipids, polyesters); synthetic biobased polymers (non biodegradable bioplastics such as bio-PE, PA-11, PTT; biodegradable natural plastics such as PLA, PHA, PBS e sStarch blends, fossil-based biodegradable plastics such as PBAT and PCL. Examples of industrial application. 2 CFU
- Plastics durability: aging mechanisms (mechanical oxidation, thermal oxidation, photolysis and photo-oxidation) examples of degradation of some relevant plastics). Evaluation of span life (accelerated ageing, oxidation index, evaluation of induction time) 2 CFU
- The Problem of plastic Pollution: End-of-life management: classification of recycling typology: primary, secondary, tertiary and quaternary recycle, feedstock recycling. Overview of national and over national policies about plastic recycling (recycling of packaging, of waste electrical and electronic equipment (WEEE) of end-of-life cars (ELV). Polymer in the circular economy. Overview of Life cycle analysis. Examples 2 CFU
Lab experiences (2 CFU)
- Synthesis of polymers through different reaction mechanisms with a specific focus on sustainable, eco-friendly polymers (e.g. dextrin-based polymers)
- Preparation of biomembranes for sustainable processes and study of their properties (permeability tests),
- Preparation of biocomposites, by addition of natural fibers to a polymer matrix
- Determination of the molecular weight of polymers by viscosimetry
- Infrared and thermal characterization of polymer materials by means of FTIR, TGA and DSC analyses.
Suggested readings and bibliography
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Class schedule
Lessons: dal 03/10/2022 to 03/02/2023
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