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Sustainable Polymers and Composite

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Sustainable Polymers and Composite

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Academic year 2023/2024

Course ID
CHI0161
Teachers
Maria Paola Luda (Lecturer)
Fabrizio Caldera (Lecturer)
Francesco Trotta (Lecturer)
Adrián Matencio Durán (Lecturer)
Degree course
Materials Science [0202M21]
MaMaself
Year
2nd year
Teaching period
First semester
Type
Characterizing
Credits/Recognition
8
Course disciplinary sector (SSD)
CHIM/04 - industrial chemistry
Delivery
Class Lecture + Lab Practicals
Language
English
Attendance
Obligatory
Type of examination
Oral
Prerequisites
Priciples of Organic Chemistry, Basic of macromolecular chemistry: polymer structures; thermoplastic and thermosetting systems; Characteristic temperature for polymers systems (Glass transition melting and cristallization temperatures)
Propedeutic for
Self-sustaining teaching. Master Degree thesis of macromolecular subject
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Sommario del corso

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Course objectives

According to the Master course objectives, in this course the sustainability of polymer materials is defined. Management of polymer systems in view of a circular economy is given.

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Results of learning outcomes

Understanding the structure and the properties of sustainable polymers.

Undestanding the circular economy approach in the polymer field.

 

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Program

Theoretical part (6 CFU)

  • Definition of sustainability, sustainable polymers, Main categories of polymers: biobased and synthetic polymers 0.5 CFU
  • Plastics durability and degradation: aging mechanisms (thermal degradation, mechanical oxidation, thermal oxidation, photolysis and photo-oxidation) examples of degradation of some relevant plastics. Polymer stabilization. Evaluation of span life (accelerated ageing, oxidation index, evaluation of induction time) 1 CFU
  • The Problem of plastic Pollution: End-of-life management: classification of recycling typology: primary, secondary, tertiary and quaternary recycle, feedstock recycling. Overview of national and over national policies about plastic recycling (recycling of packaging, of waste electrical and electronic equipment (WEEE) of end-of-life cars (ELV). 1.5 CFU
  • natural polymers (proteins, polysaccharides, lipids, polyesters); synthetic biobased polymers (non biodegradable bioplastics such as bio-PE, PA-11, PTT; biodegradable natural plastics such as PLA, PHA, PBS e sStarch blends, fossil-based biodegradable plastics such as PBAT and PCL. Examples of industrial application. 3 CFU
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Lab experiences (2 CFU)

  • Synthesis of polymers through different reaction mechanisms with a specific focus on sustainable, eco-friendly polymers (e.g. dextrin-based polymers)
  • Preparation of composites, by dispersion of additives in a polymer matrix
  • Determination of the molecular weight of polymers by viscosimetry
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Course delivery

The course is delivered as:

face to face lectures: 48 h

and laboratory experiences: 32h

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Learning assessment methods

Exam is an oral interview during 30-45 min

The evaluation of the laboratory notebook will contribute to the definition of the final grade

Suggested readings and bibliography

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Notes provided by the teachers and available on the Moodle platform.

For the laboratory part, notes provided by the teachers at the beginning of the laboratory classes.



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Class scheduleV

Lessons: from 03/10/2022 to 03/02/2023

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    Enrollment opening date
    24/09/2023 at 00:00
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